By H. Fischer (auth.), H. Fischer (eds.)
Volume II/26 supplementations the former compilations II/l, II/9 and II/17 of the magnetic houses of loose radicals that have been released in 1965, 1977–1980 and 1986–90. end result of the nonetheless speedy development of the sphere and the required inclusion of recent matters the quantity is split into subvolumes in an effort to look in quick succession. including the sooner courses quantity II/26 bargains an updated and entire survey and number of constructions and knowledge at the very important chemical intermediates, particularly radicals, polyradicals and similar species equivalent to carbenes, nitrenes, and so on. As ahead of the species were grouped based on chemical points. The contents of the person subvolumes are indicated at the within front covers. for every workforce of gear the literature has been compiled and extracted by means of specialists within the fields. A small overlap among the chapters is intentional and permits a greatest of coherence and comprehensiveness of the exhibit. we want to thank the entire authors for his or her cautious and skilled paintings and the main agreeable cooperation, the Landolt-Börnstein workplace, in particular Mrs. A. Endemann, for the layouts and the untiring and cautious checking of manuscripts and galley proofs, and Springer-Verlag for the conventional care within the training of the amount that's released with out exterior monetary aid. Zürich, December 2003 The Editor desk of contents Magnetic homes of loose Radicals Subvolume E: Phosphorus-Centered Radicals, Radicals headquartered on different Heteroatoms, natural Radical Ions half 2 I creation I normal advent [H. Fischer]. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 A Definition and components . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
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Extra resources for Phosphorus-Centered Radicals, Radicals Centered on Other Heteroatoms, Organic Radical Ions. Part 2
Sample text
428 ESR / 270 In equilibrium with the di-isonitrile complex; see [C32H38CuN2O2]• below. 30 ESR / 320 Below about 250 K, the CuI complex is in equilibrium with its CuII valence tautomer. 4 3,6-Disubstituted 1,2-benzosemiquinones 3 Substance Generation / Matrix or Solvent / Method / T [K] g-Factor / a-Value [mT] Ref. / add. Ref. 022 ESR / 270 In equilibrium with the mono-isonitrile complex; see [C23H29CuNO2]• above. 4 3,6-Disubstituted 1,2-benzosemiquinones Substance Generation / Matrix or Solvent / Method / T [K] g-Factor / a-Value [mT] Ref.
Ref. 0046 96Har C(CH3)3 O CO OP(C6H5)3 Re I CO O CO 4 (CH3)3 C 185/187 Re: ca. 33 mT. 3 3,5-Disubstituted 1,2-benzosemiquinones 21 Substance Generation / Matrix or Solvent / Method / T [K] g-Factor / a-Value [mT] Ref. / add. Ref. 3 3,5-Disubstituted 1,2-benzosemiquinones Substance Generation / Matrix or Solvent / Method / T [K] g-Factor / a-Value [mT] Ref. / add. Ref. 3 3,5-Disubstituted 1,2-benzosemiquinones 23 Substance Generation / Matrix or Solvent / Method / T [K] g-Factor / a-Value [mT] Ref.
94. 3 3,5-Disubstituted 1,2-benzosemiquinones Substance Generation / Matrix or Solvent / Method / T [K] g-Factor / a-Value [mT] Ref. / add. Ref. 3 3,5-Disubstituted 1,2-benzosemiquinones 15 Substance Generation / Matrix or Solvent / Method / T [K] g-Factor / a-Value [mT] Ref. / add. Ref. 3 3,5-Disubstituted 1,2-benzosemiquinones Substance Generation / Matrix or Solvent / Method / T [K] g-Factor / a-Value [mT] Ref. / add. Ref. 3 3,5-Disubstituted 1,2-benzosemiquinones 17 Substance Generation / Matrix or Solvent / Method / T [K] g-Factor / a-Value [mT] Ref.