By Akira Harada
Proposing the paintings of pioneering specialists during this intriguing box of supramolecular polymer chemistry, this monograph covers an in depth variety of functions, together with drug supply and catalysis. It makes a speciality of new constructions and phenomena of cyclodextrin-based supramolecular polymers and lots of different compound periods. whereas offering a deeper perception in macromolecular popularity and the mechanisms of residing platforms, this booklet additionally introduces attention-grabbing novel phenomena past normal systems.Content:
Chapter 1 a number of Hydrogen?Bonded Supramolecular Polymers (pages 1–28): Wilco P. J. Appel, Marko M. L. Nieuwenhuizen and E. W. Meijer
Chapter 2 Cyclodextrin?Based Supramolecular Polymers (pages 29–50): Prof. Akira Harada and Yoshinori Takashima
Chapter three Supra?Macromolecular Chemistry: towards layout of recent natural fabrics from Supramolecular Standpoints (pages 51–70): Kazunori Sugiyasu and Seiji Shinkai
Chapter four Polymerization with Ditopic Cavitand Monomers (pages 71–93): Francesca Tancini and Enrico Dalcanale
Chapter five Polymers Containing Covalently Bonded and Supramolecularly connected Cyclodextrins as aspect teams (pages 95–126): Helmut Ritter, Monir Tabatabai and Bernd?Kristof Muller
Chapter 6 Antibody Dendrimers and DNA Catenanes (pages 127–149): Hiroyasu Yamaguchi and Prof. Akira Harada
Chapter 7 Crown Ether?Based Polymeric Rotaxanes (pages 151–182): Terry L. rate and Harry W. Gibson
Chapter eight Processive Rotaxane Catalysts (pages 183–193): Johannes A. A. W. Elemans, Alan E. Rowan and Roeland J. M. Nolte
Chapter nine rising Biomedical services via ‘Mobile’ Polyrotaxanes (pages 195–204): Nobuhiko Yui
Chapter 10 Slide?Ring fabrics utilizing Polyrotaxane (pages 205–229): Kazuaki Kato and Kohzo Ito
Chapter eleven Stimuli?Responsive structures (pages 231–267): Akihito Hashidzume and Prof. Akira Harada
Chapter 12 actual natural Chemistry of Supramolecular Polymers (pages 269–291): Stephen L. Craig and Donghua Xu
Chapter thirteen Topological Polymer Chemistry: A Quest for unusual Polymer jewelry (pages 293–303): Yasuyuki Tezuka
Chapter 14 constitution and Dynamic habit of Organometallic Rotaxanes (pages 305–329): Yuji Suzaki, Tomoko Abe, Eriko Chihara, Shintaro Murata, Masaki Horie and Kohtaro Osakada
Chapter 15 Polyrotaxane community as a Topologically Cross?Linked Polymer: Synthesis and homes (pages 331–346): Toshikazu Takata, Takayuki Arai, Yasuhiro Kohsaka, Masahiro Shioya and Yasuhito Koyama
Chapter sixteen From Chemical Topology to Molecular Machines (pages 347–359): Jean?Pierre Sauvage
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Extra resources for Supramolecular Polymer Chemistry
Sample text
10) [48]. Linear supramolecular polymers formed by 6-CiO-a-CD or 3-CiNH-a-CD demonstrate that the viscosity of supramolecular polymers is lower than that expected from the molecular weight of the supramolecular polymers. The introduction of branched units likely plays an important role in obtaining viscous supramolecular systems. 3-Cinnamoylaminohexanamide-a-CD (3-CiHexNH-a-CD) and 3-Nacinnamolyaminohexancarbonyl-Ne-cinnamoyl-lysinamide-a-CD (3-(N-CiHexNHN-CiLys)-a-CD) bearing two guest parts have been employed to improve the degree of polymerization as well as the physical properties [49].
And Stadler, R. (1991) Makromol. , and Stadler, R. (1992) Angew. Makromol. , 261–282. , and Hayes, W. (2010) Macromolecules, 43, 2512–2517. , and Sivakova, S. (2003) J. Polym. J. (2005) J. Am. Chem. , 127, 18202–18211. -C. (2010) Macromolecules, 43, 1245–1252. W. (2006) Macromolecules, 39 (13), 4265–4267. P. P. (2008) J. Polym. Sci, Part A, 46, 3877–3885. W. (2010) Chem. Eur. , 16, 1601–1612. W. W. (2006) Biomaterials, 27, 5490–5501. A. (2010) Macromol. , 10, 1345–1354. E. (1999) Chem. W. (2008) J.
The incorporation of UPy-functionalized cell adhesion peptides into the supramolecular biomaterial increased cell adhesion, spreading, and proliferation compared to the bare construct, revealing the applicability of this approach. 19 Modular approach to supramolecular biomaterials using the noncovalent interactions for the anchoring of bioactive molecules. Reprinted with permission from Nature Publishing Group [56a]. 20 Supramolecular polymers based on the benzene-1,3,5-tricarboxamide motif (left) and the nano-fibers as observed with AFM (phase image, 450 Â 450 nm, right).