By Juan M. D. Tascón, Maria A. Diez, Ángeles G. Borrego
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Extra info for Proceedings of the International Conference on Coal Science & Technology 2011
Example text
3]). Figure 1. Schematic diagram showing main characteristics of spin population vs. temperature diagrams [3]. (Reproduced with permission: Carbon 1989, 27, 197; Copyright 1989 Elsevier) 19 Table 1 ESR parameters of coals given as “spin populations x 10 ” in the flow cell [3]. In coal liquefaction, extract yields increase and molecular mass distributions get broader as the temperature reaches 375-400°C [4, 5]. This range is well above the 310 – 340 °C interval signalled for the onset of covalent bond cleavage, suggesting that several bonds must rupture before large molecular fragments are released from the solid matrix.
03 Riaza, J. 12 Ruiz, B. 06 Riley, G. A28, B31 Ruiz, E. G. B51, C02 Runstedtler, A. A02 Rodrigo-Naharro, J. A10 Russell, D. B02 Rodrigues, R. B67 Russig, S. C02 Rodríguez Acevedo, E. S. 08 Šafářová, M. 34 Shishido, T. C01, C48 Saha, C. A45 Shoji, M. C46 Sakai, K. C01, C48 Shui, H. C32 Sakimoto, N. A21, C52 Shui, H. C12 Sakurovs, R. O. 05 Salamanca, M. B04 Simonyi, T. B61 Salatino, P. V. B61 Saldaña, R. A10 Slavinskaya, N. B52 Saloojee, F. E. A03, A52, B29, C04, C65 Sánchez, A. M. M. A50, A67 Solimene, R.
Coal utilization has potential to pollute and activities aiming to clean up past pollution, as well as mitigating the environmental consequences of future utilization are necessary. In my opinion, however, the emphasis given to CO2 capture and sequestration needs to be critically re-evaluated. Statistics show that worldwide coal production and utilization is vast and expanding. The need to support a component of research aiming to make utilization more efficient and less polluting is self evident.