Organometallics in Organic Synthesis: Aspects of a Modern by Peter Hofmann (auth.), Prof. Dr. Armin de Meijere, Prof. Dr.

By Peter Hofmann (auth.), Prof. Dr. Armin de Meijere, Prof. Dr. Heindirk tom Dieck (eds.)

More and extra attainable functions of organometallic compounds in natural synthesis were exposed and progressively more scientists are drawn to this quarter of analysis. This booklet provides an state of the art account of the winning software of major- and transition steel mediated syntheses. it's going to stimulate new rules and start up extra examine in all parts of this attention-grabbing chemistry.

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Inorg Chim Acta 104: 51-54 Antberg M, Dahlenburg L (1986(a» Metallabhangigkeit von Cyclometallierung und Aren-C-H-Aktivierung bei der Photolyse von cis-H2M(PCH2CH2CH2PMe2)3 (M = Fe, Ru) in Benzol. Angew Chern 98: 247248; Angew Chern Int Ed Engl 25: 260-261 Antberg M, Dahlenburg L (1986(b) Halo and Hydro Complexes of Ruthenium(II) Containing the Novel Tripod Tetrakis(teriary) Phosphine P(CH 2CH 2CH 2PMe 2 )3· Inorg Chim Acta 111: 73-76 Antberg M, Dahlenburg L (1986(c» Spaltung olefinischer und aliphatischer C-H-Bindungen bei der Reduktion von RuCl2(P(CH2CH2CH2PMe2)3 in Cyclopenten und Tetrahydrofuran.

Right). 34 of 33 (left) and of the Pt(dtbpm) The accessibility of Pt(dtbpm)Clz (33) now opens up interesting perspectives of the chemistry of the 14 electron intermediate Pt(dtbpm) (34). We have also performed EH model calculations for 34 and for its C2H4 derivative 35 in order to compare the results to those for the corresponding parent molecules 25 and 27. Not unexpectedly the four t-butyl groups enhance the n donor capacity of the Pt (0) fragment. 5 eV higher for 34 than for 25 and all trends already discussed on going from 26 to 27 (see Fig.

C~Me~ )-dicarbonyl-rhodium and -iridium Complexes. J Chem Soc, Chem Commun 1984: 624-626 Saillard JY, Hoffmann R (1984) C-H and H-H Activation in Transition Metal Complexes and on Surfaces. ,~-CoHo)Ir(CO)H2. ,~-C~H~)3Ir3 (CO)3. Inorg Chem 21: 1701-1702 Silvestre J, Calhorda MJ, Hoffmann R, Stoutland PO, Bergman RG (1986) Some Problems in the Oxidative Addition and Binding of an Ethylene to a Transition Metal Center. Organometallics 5: 1841-1851 Thompson ME, Baxter SM, Bulls AR, Burger BJ, Nolan MC, Santarsiero BD, Schaefer WP, Bercaw JE (1987) "0 Bond Metathesis" for CH Bonds of Hydrocarbons and Sc-R Bonds of Permethylscandocene Derivatives.

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