By H. Fischer (auth.), H. Fischer, K.-H. Hellwege (eds.)
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With dimethylurea (Ti:H,O,)/ 30 iz4) Assignment tentative, probably H (6). iz5) Species from deamination of the peptide also observed.
30 72Becl UV-irr. 4 64Maal Reaction of HO. / add. Ref. 9 Primary alkyl radicals of type RCH, For For For For CW-Wl’+ CH&H2C+(OH)CH2 lGWW HO,CCH,C(OH)(CO,H)CH, cc;g2;g 3 2 W-bF,l’ CF,CF,CH, CWU’ Prop-2-ynyl HC=CCH, CW-VT CH,CIC=CCH, R = H, n-Alkyl: R=CH,R’: R=CHR’R’. 1 Acyclic substituent R. Leading atom is carbon y-irr. 23 (2) 71Zell/ 66Cor2, 75Vasl Reaction of TESI. with the bromide/ Cyclopropane? 99 70Bowl/ 73Bidl p-irr. 49 70Bowl “) Equal hfs measured for analogous radicals from n-propyl- and n-butyl-methylketone.
113) Deuterated species also studied. 114) Maximum principal value. 2 Acyclic substituent R. Leading atom is not carbon y-irr. 0023 Polycrystalline 77 [CH,ASO,]‘~2-0,AsCH2 KW,B~H, g-Factor at 77 K/ y-irr. 003 EPR/ 77 y-irr. of methylbromide at 77 K/ Solid methylbromide, polycrystalline EPR/ 77 y-irr. of methyl bromide/ Solid perdeuteromethanol EPR/ ? 5 ‘141 Substance %Y %F? / add. Ref. p-irr. 28 71Micl y-irr. 3 115) 73Aysl e-irr. 085 69Kru3 Reaction of TBO. 150 69Hud4 X-irr. 15 69Hud4 Ce(IV) photooxidation acetic acid at 77 K/ Hz0 CCA,,Gel W,),G~H, CW-LGel V-We(CH3)2~H2 ‘I’) Maximum principal value of the hfs-tensor.