New Directions in Sorption Technology by George E. Keller II

By George E. Keller II

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Rapid expansion in number of uses commercialized. Acceptance by plants. " 3 Optimization Technology becomes standardized to one or a very few embodiments. Fil1-in-thegaps research. Slowdown in the rate of improvement. Many large-scale uses but sharp decline in the rate of applications to new uses. Stage 56 Technological Maturity of Sorption Processes and Sorbents Table I I I . 5 cm Phase angle: 45° (short-stroke piston leads) Adsorbent: 83 g of 13X molecular sieve, 40x80 mesh Feed pressure: 200 KPa Cycle frequency: 30 rpm Technological Maturity of Sorption Processes and Sorbents Stage 1 Discovery/ Innovation Stage 3 Optimization Effort Figure 1 .

Temperature-Swing Adsorption (TSA). TSA (see Figure 3), which can be practiced with both liquid and gas feeds, is usually only practical when the adsorbate is a small percentage (usually less than about 10 weight percent) of the stream. This is because turnaround times for such processes can range from several hours to over a day, and only when the adsorbate concentration in the feed is low can the on-stream time be a significant fraction of the total cycle time. The heat expended in desorbing the adsorbate is also usually several times the heat of vaporization of the adsorbate.

Chem. Eng. Prog. 1983, 12. (4), 60. 33. Symoniak, M. F. Hydrocarbon Processing May, 1980, 110. 34. Kokotailo, G. ; Meier, W. M. In Properties and Applications Q_f Z e o l i t e s ; Townsend, R. , E d . ; Chemical Society: London, 1979; Special Publication No. 3 3 . 35. Flanigen, E. ; Bennett, J. ; Grose, R. ; Cohen, J. ; Patton, R. ; Kerchner, R. ; Smith, J. V. Nature 1978, 211, 512. 36. Wilson, S. ; Lok, B. ; Messina, C. ; Cannan, T. R; Flanigen, E. M. J. Am Chem. Soc. 1982, I M , 1146. 37. Messina, C.

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