By Hiroyuki Suga (auth.), Kiyoshi Matsumoto, Naoto Hayashi (eds.)
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2 Host–Guest Behaviour............................................................................................... 1]nonane Derived Systems................................................................ 1 Synthesis.................................................................................................................... 2 Host–Guest Behaviour............................................................................................... 8 Conclusions.........................................................................................................................
66] and Zuo et al. 17). Theoretical investigations on anion/p interactions were also performed by Quiñonero et al. [68]. 59 Å (DF-DFT). Kim et al. 48 kcal mol−1, respectively [69]. They emphasized that both electrostatic and inductive forces contribute significantly in anion/p interactions. In comparison to cation/p interactions, dispersion force is relatively important, especially in complexes of CN− and CO32−. An important contribution of inductive forces to anion/p interactions is also proved by the fact that the anion/p interaction energies of 1,3,5-triazine–halogen anion complexes are larger than those expected on the basis of permanent quadruple moment of 1,3,5-triazine.
CSD analysis revealed that, although the interaction energies are larger, OH/p and NH/p interactions do not appear as frequently as CH/p interactions in crystalline [35]. This is because, while the CH group is only capable of participating in CH/p interactions, OH and NH groups can not only be involved in OH/p and NH/p interactions but also in traditional hydrogen bonds. Due to the larger interaction energy, OH and NH groups preferably form traditional hydrogen bonding. Thus, OH/p and NH/p interactions are less frequently encountered than expected from the interaction energies.