By Chao?Jun Li, Tak?Hang Chan(auth.)
An intensive replace of the vintage reference on natural reactions in water
released virtually a decade in the past, the 1st version has served because the consultant for study during this burgeoning box. as a result expense, security, potency, and environmental friendliness of water as a solvent, there are various new purposes in and educational laboratories. greater than 40 percentage of this generally up-to-date moment version covers new reactions. For ease of reference, it truly is prepared via sensible teams. A center reference, finished natural Reactions in Aqueous Media, moment Edition:
* offers the main entire insurance of aqueous organicreactions available
* Covers the elemental ideas and thought and progresses to applications
* contains alkanes, alkenes, aromatics, electrophilic substitutions, carbonyls, alpha, beta-unsaturated carbonyls, carbon-nitrogen bonds, natural halides, pericyclic reactions, photochemical reactions, click on chemistry, and multi-step syntheses?
* offers examples of purposes in industry
this is often the finest reference for chemists and chemical engineers in or examine, in addition to for college kids in advanced-level courses.Content:
Chapter 1 creation (pages 1–13):
Chapter 2 Alkanes (pages 15–24):
Chapter three Alkenes (pages 25–75):
Chapter four Alkynes (pages 77–128):
Chapter five Alcohols, Phenols, Ethers, Thiols, and Thioethers (pages 129–149):
Chapter 6 natural Halides (pages 151–180):
Chapter 7 fragrant Compounds (pages 181–195):
Chapter eight Aldehyde and Ketones (pages 197–277):
Chapter nine Carboxylic Acids and Derivatives (pages 279–292):
Chapter 10 Conjugated Carbonyl Compounds (pages 293–320):
Chapter eleven Nitrogen Compounds (pages 321–354):
Chapter 12 Pericyclic Reactions (pages 355–407):
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Additional resources for Comprehensive Organic Reactions in Aqueous Media, Second Edition
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The reaction was extended to atom-transfer radical polymerization (ATRP) by changing the monomer/halide ratio and could take place in aqueous media (Eq. 2 Radical Additions The addition of carbon-based radicals to alkenes has been shown to be successful in water. Thus, radical addition of 2-iodoalkanamide or 2-iodoalkanoic acid to alkenols using a water-soluble radical initiator in water generated γ-lactones (Eq. 119 In addition to carbon-based radicals, other radicals such as sulfur-based radicals, generated from RSH-type precursors (R = alkyl, acyl) with AIBN, also smoothly add to α-allylglycines protected at none, one, or both of the amino acid functions (NH2 and/or CO2 H).