Chapter 1 spouse elements in ldl cholesterol of varied assets (pages 1–26): Louis F. Fieser
Chapter 2 The Chemistry of Lanosterol (pages 27–38): D. H. R. Barton
Chapter three The Ergosterol path to Adrenal Cortical Hormones (pages 39–45): H. B. Henbest and E. R. H. Jones
Chapter four Investigations at the Synthesis of 11?Ketosteroids (pages 46–58): H. Heusser and O. Jeger
Chapter five Partial Synthesis of ?9(11)?Anhydrocorticosterone Acetate (pages 59–64): R. Casanova, A. Ruff and C. W. Shoppee
Chapter 6 Cortisone and 11?Epi?17?Hydroxycorticosterone Diacetate from Sarmentogenin (pages 65–78): A. Lardon and T. Reichstein
Chapter 7 Synthesis of 11?Oxygenated Steroids from Steroidal Sapogenins (pages 79–95): Carl Djerassi and G. Rosenkranz
Chapter eight 11?Oxygenated Steroids from Ergosteryl?D Acetate 22:23?Dibromide (pages 96–103): F. S. Spring, G. T. Newbold, R. C. Anderson, R. Budziarek, F. Johnson, J. A. Mcewan, D. Maclean and R. Stevenson
Chapter nine advent of the 11?Keto functionality within the Steroids (pages 104–109): J. M. Constantin and L. H. Sarett
Chapter 10 The Characterization of Trisubstituted Steroidal Olefines by means of Infra?Red Spectroscopy (pages 110–126): H. Hirschmann
Chapter eleven a few elements of the Stereochemistry of C?20 (pages 127–141): W. Klyne
Chapter 12 The Chemical motion of X?Rays on a few Steroids in Aqueous platforms (pages 142–160): Joseph Weiss
Chapter thirteen Biogenesis of Adrenal Cortical Hormones (pages 161–175): Oscar Hechter
Chapter 14 reviews of the Enzymes inquisitive about the Synthesis and Degradation of the Hormones of the Adrenal Cortex (pages 176–190): Leo T. Samuels
Chapter 15 The in vitro Synthesis of Adrenal Cortical Steroids (pages 191–209): Ralph I. Dorfman, Mika Hayano, Robert Haynes and Kenneth Savard
Chapter sixteen Species variations and different components Influencing Adrenocortical Secretion (pages 210–232): I. E. Bush
Chapter 18 In vivo Metabolism of Adrenosterone (pages 233–239): Ralph I. Dorfman, Kenneth Savard and Shlomo Burstein
Chapter 18 present prestige of Corticosteroid Metabolism in guy (pages 240–260): G. Pincus, E. B. Romanoff and Louise P. Romanoff
Chapter 19 Estimation of person Adrenocortical Hormones in Human Peripheral Blood (pages 261–271): C. J. O. R. Morris and D. C. Williams
Chapter 20 Corticosteroid Metabolism in remoted Perfused Rat Livers (pages 272–289): Oscar Hechter
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Additional resources for Ciba Foundation Symposium - Synthesis and Metabolism of Adrenocortical Steroids (Colloquia on Endocrinology), Volume VII
Clayton, A. Crawshaw, C. W. Greenhalgh, Dr. B. J. Lovell, Dr. G. Silverstone, G. W. Wood and Dr. G. F. Woods. The authors are indebted t o Glaxo Laboratories Ltd. for both financial support and for the preparation of intermediates by Dr. B. A. Hems and his colleagues. , and STEVENS,P. G. (1948). J. org. , 13,lO. FIESER, L. F. (1950). Experientia, 6, 312. , (1930). , 477, 268. 44 GENERALDISCUSSION DISCUSSION FIESER:What is the essence of your evidence for the configuration at 5 and 8 in the 5:8-diol?
And SCHINDEL, L. (1930). Hoppe-Seyl. Z . , 192, 73. WINDAUS, A. (1906). Ber. dtsch. chem. , 39, 2249. , and AUHAGEN, E. (1929). , 412, 185. , and BRUNKEN, J. (1928). , 460, 225. Fr. (1935). , and SCHENK, 98. , and NAGGATZ, J. (1939). , 542, 204. , and NEUKIRCHEN, K. (1919). Ber. dtsch. chem. , 52, 1915. , and RESAU,C. (1963). Ber. dtsch. chem. , 46, 1246. , and MOORE,M. (1943). J . Am&. chem. ,65, WINTERSTEINER, 1518. DISCUSSION MARRIAN:It will be very interesting when some of these accompanying substances are tested biologically.
HEUSSER:Yes. DJERASSI:This would constitute a violation of the isoprene rule. HEUSSER:Yes. We believe that the methyl group on C-14 has an influence on the ketone group a t C-17 in the trans C / O series. We don’t believe that the point of attachment of the long side chain is really C-15. BARTON:What about the methyl ketone, Dr. Heusser? Will your atomic models tell you that it can be hindered in the same way? HEUSSER:It is sterically hindered, but not so strongly that it is a reason for making a definite assignment of the position of the side chain.