By J. Buckingham, R. A. Hill (auth.)
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Written by way of an skilled editor greatly acclaimed in the clinical group, this booklet covers every thing from oxygen to nitrogen functionalities. From the contents: Palladium-Catalyzed Syntheses of 5-membered Saturated Heterocycles The Formation of Carbon-Sulfur and Carbon-Selenium Bonds by means of Substitution and Addition Reactions Catalyzed by means of Transition steel Complexes Palladium-Catalysis for Oxidative 1,2-Difunctionalization of Alkenes Palladium-Catalyzed Formation of fragrant Heterocycles Rhodium-Catalyzed Amination of C-H-Bonds Transition Metal-Catalyzed Synthesis of Heterocycles Copper-Catalyzed Synthesis of Azoles Palladium(II)-Catalyzed C-N Bond Formation regarding Aminopalladation of Aklenes Carbon-Heteroatom Bond Formation by way of Rh(I)-Catalyzed Ring-Opening Reactions fresh Advances in Homogeneous Gold Catalysis: Formation of Carbon-Heteroatom Bonds the result's an integral resource of knowledge for the strategic making plans of the bogus routes for natural, catalytic and medicinal chemists, in addition to chemists in undefined.
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Additional info for Atlas of Stereochemistry: Absolute Configurations of Organic Molecules
5. 6. 7. 8. 9. 10. 11. 12. 13. nonon - 3 - on. (Sir ricornin) -r- ~. 11 . hydroxy-4,6'dirnolhyl- ~:~ . ,;:+::"' COOH (2R,3RH-)2'omino3-mlthylouccinic acid 7. (45,65,75)( )7· [S] CHZOH ;:;. ,;:+:;, -r- C(Z) ~ CUJ 3. ec (~l 2-corbolylic acid. 1  CHZCOOH 4. (S)-H2,5-dimlthyl' c ycloplnt - 2 - In· , .. on• . CH =CH 2 J-~H [~) Mi o 2. oo .. 8 . ~ (6) +COOH (0) CUlCl) (CHZ~,CH3 (CHol)z r-r COOH COOH -eCl) (12) NH 2 H3C+C2H~ Ph --- (RH+) 2-pnonyl '2' butylomino A 40. 8. H, [tl] N=NCH(CH 3 )2 H3C + C 2 H, Ph 17.
R)-H3'IKI b S] HO-o-OH ii 6--CH2C~OH I H, (3R,4S)-(-)4'hydroxy' cyelopenl'l'eno- 3'ocotic acid lacton. A'2~ . 9 . H , i ~OH i OH ~~ . Ouc~ I 14. (IR,2R)-(-)bi"(hydro- 1 'ymothyl)cycl_ntono . O--C=C(CH2~CH~ I~. (IR, ZS)-(-)Z'(I-aetynyl) cycloponlonol. --J C ( 4) --- 1[6) ORD  16. lhylcycloptlnton • . L 2. 3. 4. 5. 6. (IR, 2RH-)1,2·dimolhylcyclopontane A 31. 9 . 17. CR)-(-)2'mothyl methyl,neeyclo' pintone. (RH-) 2·molhylcyclopontanono. IO . D. Varech, C. Ouannes and J. Jacques, Bull. SOC. Chirn. , 1965, 1662.
S] HO-o-OH ii 6--CH2C~OH I H, (3R,4S)-(-)4'hydroxy' cyelopenl'l'eno- 3'ocotic acid lacton. A'2~ . 9 . H , i ~OH i OH ~~ . Ouc~ I 14. (IR,2R)-(-)bi"(hydro- 1 'ymothyl)cycl_ntono . O--C=C(CH2~CH~ I~. (IR, ZS)-(-)Z'(I-aetynyl) cycloponlonol. --J C ( 4) --- 1[6) ORD  16. lhylcycloptlnton • . L 2. 3. 4. 5. 6. (IR, 2RH-)1,2·dimolhylcyclopontane A 31. 9 . 17. CR)-(-)2'mothyl methyl,neeyclo' pintone. (RH-) 2·molhylcyclopontanono. IO . D. Varech, C. Ouannes and J. Jacques, Bull. SOC. Chirn. , 1965, 1662.