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By Eric Bartholomew, Research Chemist, Avery Dennison Performance Adhesive Center he prevailing trend toward the use of lighter weight and lower cost engineered plastics in automotive, construction, aerospace, electronics, and other industrial uses has created a need for pressure-sensitive materials that can bond well to these new, inherently low-surface-energy (LSE) plastics. This article discusses novel, all-acrylic compositions with inherently lower surface energy that display significantly improved adhesion to LSE substrates such as polyethylene and polypropylene.
Terpene resins are produced by oligomerization of pinene and limonene to produce non-polar tackifiers with a low molecular weight and a high softening point. Terpene resins are not commonly used in acrylic PSAs because, traditionally, they have very limited solubility in acrylics containing polar monomers. However, when low-solubility acrylic monomers are used to design an acrylic PSA, like those of the LSE Type 2 and Type 3 mentioned previously, these non-polar tackifers become useful. Table 9 (p.
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